Physico-chemical water treatment

Robust treatment for a wide range of wastewater streams

Physico-chemical water treatment is a well-established technique for treating complex industrial wastewater streams. By combining targeted chemical dosing with physical separation processes, we remove heavy metals, suspended solids and other poorly degradable components, among others. Depending on the application (inline or batch), we design installations that achieve the required water quality while keeping operating costs to a minimum.

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The building blocks of efficient treatment

An optimal physico-chemical installation is always tailor-made. Based on laboratory and pilot tests, we determine the ideal configuration of the following process steps.

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Coagulation, neutralisation & flocculation

This forms the basis of every physico-chemical installation. The aim is to precipitate pollutants into a sludge fraction that can easily be separated.

  • Coagulation: The first step, in which we neutralise the electrical charge of particles by dosing a coagulant. 
  • Neutralisation: Through precise pH control, often using milk of lime or sodium hydroxide, we form hydroxides that cause unwanted substances to precipitate out of solution. 
  • Flocculation: Adding a polyelectrolyte causes micro-flocs to bind together into large, robust flocs that are easier to separate. 

Detoxification

For specific industrial streams containing toxic components, specialised pretreatment is indispensable. We focus on chemical conversion into safe, precipitable forms that can easily be separated.

  • Chromium(VI) reduction: We reduce toxic Cr(VI) to the more manageable Cr(III). 
  • Cyanide detoxification: Cyanides are rendered harmless by means of a controlled oxidation process. 
  • Heavy metals: For metals that do not form hydroxides (such as mercury or arsenic), we use specific reagents. 
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pH & redox control

Accurate measurement and control are essential for stable, reliable process operation. Continuous monitoring means deviations are detected immediately and corrected automatically, ensuring efficient chemical consumption without overdosing.

  • pH control: We select the right probe specifically for your medium and automate the dosing of acids or alkalis. 
  • Redox measurement: Ensures reliable process control during chemical conversion reactions such as oxidation, reduction and detoxification.
  • Automation: Our controllers link the measured values directly to the dosing pumps for applications such as chlorine disinfection or chromium reduction. 
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Sludge separation

Once the flocs have formed, they must be separated from the treated water. The choice of technology depends on the sludge concentration and the flow rate.

  • Settling (sedimentation): The classic method, in which sludge is separated at the bottom of the installation. 
  • Lamella clarifier: Ideal where space is limited; inclined plates increase the effective settling area, allowing us to handle high flow rates on a minimal footprint. 
  • Flotation (DAF): An alternative in which micro air bubbles carry the sludge to the surface. Ideal for light sludge or high hydraulic loads. 
Active carbon filter

Post-treatment

As a final step, post-treatment can be used to remove residual contaminants from the water and guarantee a consistent final quality.

  • Sand filtration: removes residual suspended solids and fine particles from the treated water.
  • Activated carbon filtration: adsorbs dissolved organic substances as well as colour, odour and taste compounds, and can be used to target specific residual contaminants.

Depending on the required water quality, both techniques can be applied separately or in combination.

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Dewatering

The separated sludge still contains a large amount of water. Dewatering the sludge further greatly reduces its volume and keeps transport and disposal costs down.

  • Chamber filter press: presses the sludge between filter plates under pressure, forming a relatively dry filter cake.
  • Centrifuge: continuously separates water and solids based on their difference in density.
  • Vacuum belt filter: continuously dewaters the sludge by drawing it over a filter cloth using vacuum.

The most suitable technique is selected based on factors including the sludge type, the sludge volume and the required dry solids content.

Why choose PCA Water?

From lab to practice

No guesswork. We size installations based on pilot tests and years of experience.

Automation

Our installations operate autonomously, greatly reducing the need for manual supervision and the risk of errors.

Complete solution

Alongside the treatment itself, we also integrate the necessary dosing systems and post-treatment technologies.

Where do we apply this technology?

Physico-chemical water treatment is used in a wide variety of industrial processes where reliable removal of specific components is required. Depending on the composition of the wastewater, we tailor the process steps and chemical conditioning to the required water quality and discharge requirements.

Heavy metals

Removal of metals such as nickel, copper, zinc, cobalt… through chemical precipitation and sludge separation.

Suspended solids

Separation of suspended particles that cause turbidity, deposits or operational problems.

Chromium(VI)

Reduction of toxic Cr(VI) to Cr(III), followed by precipitation and separation.

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Sulphates and phosphates

Sulphates and phosphates can be removed from wastewater through physico-chemical treatment by converting them into poorly soluble compounds. Targeted reagent dosing at the optimum pH precipitates these components, after which the resulting sludge is separated.

From analysis to a concrete solution: laboratory evaluation

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The right physico-chemical water treatment starts with a thorough analysis. Not every wastewater stream responds in the same way, which makes a targeted laboratory evaluation essential for determining the most efficient treatment.

In our in-house laboratory, we carry out extensive tests on your water samples to evaluate various treatment methods, such as neutralisation, coagulation, flocculation, precipitation and sludge separation. This gives us insight into the technical feasibility, the chemicals required and the expected treatment results.

Thanks to our hands-on experience, we quickly translate laboratory results into a concrete, feasible solution for your specific water challenge.

FAQ: frequently asked questions about physico-chemical treatment

Is a laboratory or pilot test always necessary?

Although we can draw on our experience from previous projects for many standard wastewater streams, every situation is different. For complex or highly variable wastewater, we therefore recommend laboratory or pilot trials, so that we can size the installation correctly and optimise chemical consumption.

What is the advantage of a lamella settler over a conventional settler?

A lamella settler is the ideal solution where space is limited; the use of inclined plates greatly increases the effective settling area, allowing a much higher flow rate to be treated on a fraction of the normal footprint.

One point to note is that the lamellae can become fouled or clogged more quickly, so regular inspection and cleaning may be necessary.

What is the fundamental difference between a settler and a flotation unit?

The difference lies in the direction of separation: in a settler, the sludge formed sinks to the bottom, whereas in flotation (DAF) the sludge is carried to the surface by micro air bubbles. The choice depends on the specific type of contamination and the flow rate.

Can a physico-chemical installation operate fully autonomously?

Yes, our systems are equipped with extensive automation as standard to reduce operating costs and human error. Thanks to precise pH and redox control, the installation continuously adapts to the incoming contaminant load. As a result, operator intervention can in many cases be limited to inspections and periodically emptying the chamber filter press.

How do you deal with toxic substances such as cyanide or hexavalent chromium?

These require a specific detoxification step before they can be precipitated. We use controlled oxidation for cyanides and reduction processes to convert hexavalent chromium (Cr-6) into the less harmful trivalent chromium (Cr-3), which can then be safely precipitated and separated.

Experience the difference with PCA Water.

Would you like to know how physico-chemical treatment can help you reliably meet your discharge limits? Contact us for a consultation or a laboratory analysis.

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